The pH of Ozone Water: Maintaining Neutrality for Optimal Performance

The pH value of ozone water is typically around 7.0, indicating a neutral balance. This means that ozone water does not significantly affect the pH of the water system it is used in. Ozone is a powerful oxidizing agent that can reduce trace amounts of certain dissolved metals, such as manganese, iron, and copper, by reacting with them and raising them to their highest oxidation state, allowing them to form a precipitate that can be removed through simple particle filtration.

Understanding Ozone Water Decomposition

The decomposition of ozone in water is influenced by several factors, including temperature, pH, environment, and concentrations of dissolved matter and UV light. Ozone decays in water under drinking water conditions, partly in reactive OH-radicals, and the decay of ozone in OH-radicals in natural waters is characterized by a fast initial decrease of ozone, followed by a second phase in which ozone decreases by first-order kinetics. The half-life of ozone in water is much shorter than in air, and it is dependent on the quality of the water, ranging from seconds to hours.

Impact of Ozonation on Natural Organic Matter (NOM)

PH of ozone waterImage source: wikimedia

Ozonation can lead to changes in the structure of natural organic matter (NOM) in water, resulting in the complete oxidation of humic acids and an increase in the hydrophilic NOM fraction content. This can influence the formation of haloacetic acid (HAA) precursors in groundwater rich in NOM during drinking water treatment. Ozonation at pH 6-10 led to changes in NOM structure, i.e., complete humic acid oxidation, and increased the hydrophilic NOM fraction content (65-90% achieved using 3.0 mg O(3)/mg DOC). The highest degree of NOM oxidation and HAA precursor removal was achieved at pH 10 (up to 68% HAAFP).

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Balancing the pH of Ozone Water

To balance the pH of ozone water, one can consider using acidic or basic solutions to adjust the pH to the desired range. For example, adding a small amount of food-grade citric acid or baking soda (sodium bicarbonate) can help lower or raise the pH, respectively. However, it is important to note that any additives should be safe for consumption and not introduce any unwanted contaminants into the water.

DIY Ozone Water Generation

In terms of home remedies, one can use a simple DIY ozone generator to produce ozone water. A common design involves passing oxygen through a high voltage dielectric discharge, which breaks the oxygen molecules and forms ozone. The ozone concentration in the water can be quantified using a method based on the ability of ozone to transform indigo (blue color) into isatin (colorless).

Key Takeaways

  • The pH of ozone water is typically around 7.0, indicating a neutral balance.
  • Ozone is a powerful oxidizing agent that can reduce trace amounts of certain dissolved metals.
  • Ozone decomposition in water is influenced by temperature, pH, environment, and dissolved matter.
  • Ozonation can lead to changes in NOM structure, affecting the formation of HAA precursors.
  • To balance the pH of ozone water, one can use acidic or basic solutions, but care must be taken to ensure safety.
  • DIY ozone water generation is possible using a simple ozone generator setup.

References:
https://www.socotec.co.uk/media/faqs/faqs-how-does-ozone-water-treatment-work/
https://pubmed.ncbi.nlm.nih.gov/22875419/
https://www.lenntech.com/library/ozone/decomposition/ozone-decomposition.htm
https://www.scielo.br/j/bjft/a/pffGD9JdrfzvTJnRzGR7gVn/?format=pdf
https://www.scielo.br/j/bjft/a/pffGD9JdrfzvTJnRzGR7gVn/?lang=en
https://drinkheartwater.com/blog/ozone-water/